首页> 外文OA文献 >Influence of fictive temperature and composition of silica glass on anomalous elastic behaviour
【2h】

Influence of fictive temperature and composition of silica glass on anomalous elastic behaviour

机译:假想温度和石英玻璃成分对其影响   异常弹性行为

代理获取
本网站仅为用户提供外文OA文献查询和代理获取服务,本网站没有原文。下单后我们将采用程序或人工为您竭诚获取高质量的原文,但由于OA文献来源多样且变更频繁,仍可能出现获取不到、文献不完整或与标题不符等情况,如果获取不到我们将提供退款服务。请知悉。

摘要

In order to point out the influence of thermal history (fictive temperature)and OH content on the elastic properties of silica glass, we have performedhigh resolution in situ Brillouin spectra of SiO2 glass from room temperatureto the supercooled liquid at 1773K across the glass transition. The well knownanomalous increase of elastic modulus in the glassy state and in thesupercooled liquid regime is observed. No change of slope in the elastic moduliof silica appears as a characteristic of glass transition, on the contrary towhat happens in various other glasses. We show that thermal history has a weakeffect on elastic moduli in the glass transition regime for silica glass. Theeffect of water content in silica glass is more efficient than the fictivetemperature effect and gives larger changes in the amplitude of elastic modulusfor the same thermal dependence. A singular decrease above 1223K is alsoobserved in the shear moduli for hydrated samples. Different models explainingelastic properties temperature dependence in relationship with frozen-indensity fluctuations or with the structure are discussed.
机译:为了指出热历史(虚构温度)和OH含量对石英玻璃弹性性能的影响,我们在整个玻璃化转变过程中对SiO2玻璃从室温到1773K的过冷液体进行了高分辨率的原位布里渊光谱分析。观察到在玻璃态和过冷液体状态下弹性模量的异常增加。相反,二氧化硅的弹性模量的斜率变化没有表现出玻璃化转变的特征,这与其他各种玻璃相反。我们表明,热历史对石英玻璃的玻璃化转变过程中的弹性模量影响很小。石英玻璃中水含量的影响比虚拟温度效应更有效,并且在相同的热依赖性下,弹性模量的幅度也会发生较大变化。对于水合样品,剪切模量也观察到高于1223K的奇异下降。讨论了不同的模型,这些模型解释了弹性特性温度与冻结密度波动或结构的关系。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
代理获取

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号